Lanthanum Recycling: The Two Streams That Actually Matter (and What "Recycled La" Really Is)

Lanthanum (La) is one of the rare earths where recycling can be more than a talking point, because a big chunk of demand sits in two industrial loops that generate identifiable secondary feed: spent FCC catalysts and spent NiMH batteries. Everything else is smaller, dirtier, or too diluted to be a dependable lanthanum source.

The blunt truth about lanthanum recycling

Most "lanthanum recycling" starts as waste processing, not metal recycling.

  • The goal is usually La in a mixed rare earth product, unless you pay for extra separation.
  • Economics are driven by collection + contamination + chemistry costs, not by whether lanthanum exists in the waste.
  • USGS still describes rare earth recycling as limited overall, even though batteries and some other streams are recycled in small quantities.

1) Spent FCC catalysts: the highest-volume, most lanthanum-linked recycling stream

Why this stream is real

FCC catalysts used in petroleum refining commonly contain rare earths (especially La and Ce) as stabilizers in zeolite-based formulations. When catalysts are spent, lanthanum is still physically there, often at percent-level in the solid. Recovery has been studied for decades and is now a mature technical topic.

What "recycling" looks like in practice

Most lanthanum recovery flowsheets from spent FCC catalysts follow a recognizable pattern:

  • Pre-treatment (drying, size classification, sometimes de-oiling or removal of fines)
  • Acid leaching to dissolve La (and often other REEs) into solution
  • Selective precipitation (oxalate, phosphate, carbonate routes) to recover a REE concentrate
  • Polishing / separation only if you need high-purity lanthanum oxide rather than mixed REE output

A widely cited practical route is acid leaching followed by oxalate precipitation; one study specifically reports strong lanthanum leaching performance with nitric acid and then recovery via oxalate precipitation.

More recent work focuses on turning leach solutions into value-added lanthanum-containing products and compares process options for recovering lanthanum from FCC-catalyst leachates.

The real constraints

  • Co-dissolution of junk: Catalysts contain aluminosilicates and other components that complicate leaching and downstream purification.
  • Reagent cost and waste treatment: You are paying for chemicals and for cleaning up what those chemicals create.
  • Product form mismatch: Leaching often gives a mixed REE solution; producing battery-grade or catalyst-grade lanthanum products still needs controlled finishing.

If you see "lanthanum from catalysts" pitched as easy money, it usually ignores wastewater handling and the cost of converting a leachate into a spec product.

2) Spent NiMH batteries: lanthanum-rich anodes, strong recovery chemistry, messy logistics

Why NiMH is a good lanthanum target

NiMH anodes commonly use rare-earth metal hydride alloys where lanthanum is a major component (mischmetal-style). This makes NiMH one of the more lanthanum-dense "urban mining" streams.

What the recycling chain looks like

NiMH recycling typically starts with physical handling, then turns into hydrometallurgy:

  • Collection + sorting (separate NiMH from other batteries, remove casings)
  • Mechanical processing (shredding, separation into "black mass" or electrode powders)
  • Leaching (acids or alternative solvents) to dissolve REEs
  • Selective precipitation to recover REEs (often as phosphates or oxalates), sometimes with further separation steps

A 2022 paper reports recovery of REEs from spent NiMH using a leaching approach followed by selective precipitation, with high precipitation efficiencies for La under optimized conditions.

A 2023 review covers the broader toolbox for NiMH REE recovery and makes the same point implicitly: the chemistry is workable, but the economics are about integrated processing and separation, not a single clever step.

The real constraints

  • Collection is uneven: NiMH is not "one standardized stream" globally, and it competes with Li-ion attention and infrastructure.
  • Co-products matter: Nickel and cobalt recovery can carry the economics; lanthanum alone rarely pays for the plant.
  • Separation still decides whether you get La: Many processes output mixed REE precipitates; isolating lanthanum oxide cleanly adds cost.

3) Lamp phosphors and fluorescent powders: lanthanum exists, but it's not the easy win

Lamp phosphor powders can contain several rare earths (including La), but industrial recovery is complex and many recycling systems historically focused on safe handling and mercury management rather than rare earth separation.

If you include this stream in a lanthanum recycling narrative, keep it honest:

  • It's technically doable
  • It's operationally annoying (mix of phosphors, contaminants)
  • It often prioritizes other REEs (like Y and Eu) depending on economics

What "recycled lanthanum" usually becomes

Most real-world outputs are one of these:

  • Mixed rare earth concentrates (oxalates, phosphates, carbonates) that still need separation and finishing
  • Lanthanum oxide (La₂O₃) only when the recycler runs additional purification steps
  • Lanthanum salts (chloride/nitrate) when downstream customers want solution chemistry

In other words, recycling often substitutes for upstream mining only if the recycler can also handle part of the midstream separation and finishing burden.

Where recycling fits in the lanthanum market

Recycling can matter for lanthanum because its biggest industrial uses generate recoverable waste streams (catalysts and NiMH). But it is not a magic supply unlock:

  • It helps most when it's integrated with existing hydromet and finishing capacity.
  • It scales only as far as collection, contamination control, and waste treatment allow.
  • It reduces exposure to mining shocks, but it does not eliminate exposure to separation bottlenecks.

A foundational review of rare earth recycling highlights catalysts, NiMH batteries, and lamp phosphors as key application streams in REE recycling discussions, which lines up with the lanthanum reality.

Lanthanum recycling FAQ

1) What is the best source of recyclable lanthanum?

Spent FCC catalysts and NiMH batteries. They are the most lanthanum-linked streams with workable chemistry and realistic collection pathways.

2) Does lanthanum recycling usually produce pure lanthanum oxide?

Not usually. Many processes recover REEs as mixed precipitates first (oxalates, phosphates). Producing high-purity La₂O₃ requires extra purification and sometimes full separation steps.

3) Why isn't fluorescent lamp recycling a major lanthanum supply source?

Because the material is mixed, contaminated, and processing is complex and costly. Many lamp recycling systems historically prioritized safe handling and other recovery goals, and REE recovery has been harder to scale economically.

4) Can recycled lanthanum replace primary mining supply?

Not entirely. Recycling can reduce dependence on primary mining and provide supply diversification, but it's constrained by collection infrastructure, processing economics, and the need for separation capacity. It's best viewed as a complementary supply source rather than a complete replacement.